The areal capacitance is as high as 0.660, 0.600, 0.560, 0.480, and 0.384 F cm-2 measured at the discharge current density of 2, 4, 8, 12, and 16 mA cm-2, respectively. The cycle stability of SCs is a crucial parameter for their practical applications. The long-term stability of the electrodes was examined at 2 and 8 A g-1, and the results are shown in Figure  8a. It is found that the NCONAs electrodes capacitance retention is about 91.8% of initial value after 3,000 cycles at 2 A g-1. As illustrated in the inset of Figure  8a, the NCONAs structures were well maintained and overall preserved with little structural deformation after 3,000 cycles. The NCONAs electrode exhibits a good long-term

electrochemical stability which is further evident from the very stable charge/discharge curves for the last 10 cycles 10058-F4 concentration (Figure 

8b). The results indicated that the charge curves are still very symmetric to their corresponding discharge counterparts, showing no significant structural change of the NCONAs electrode during the charge/discharge processes. Figure 8 Cycling performance and electrochemical impedance spectra of the NCONAs supercapacitor. (a) Cycling performance of the NCONAs supercapacitor device over 3,000 cycles at 2 and 8 A g-1 (inset, the SEM of the NCONAs after 3,000 cycles at 2 A g-1). (b) The charge/discharge curves PF-01367338 manufacturer of the last 10 cycles during in 3,000 cycles for the NCONAs. (c) Cycling stability of the NCONAs at progressively various current densities. (d) Electrochemical IKBKE impedance spectra after 1st and 3,000th cycles of NCONAs. Furthermore, for a better understanding of the synergistic effect in this electrode design, the cycling performance of the NCONAs at progressively increased current density was recorded in Figure  8c. During the first 100 cycles with a charge discharge density of 2 A g-1, the hybrid structure shows a cycle stability performance and the specific capacity as high as 658 F g-1. In the following cycles, the charge/discharge rate changes successively; the hybrid structure always demonstrates stable capacitance even

suffering from sudden change of the current delivery. With the current rate back to 2 A g-1 for the rest of cycles, a capacitance of approximately 656 F g-1 can be recovered and without noticeable decrease, which demonstrates the hybrid structure has excellent rate performance and cyclability. The loss of specific capacitance may result from ineffective contacts between part of the unstable NCONAs and the following deterioration of the electron transfer and ion diffusion. To further show the PCI-32765 in vivo merits of the NCONAs and CC composite material as the electrode material, EIS provided beneficial tools to reveal the electronic conductivity during the redox process. Impedance spectra of the NCONAs electrode material were measured at open circuit potential with an AC perturbation of 5 mV in the frequency range from 0.1 Hz to 103 KHz.